I'm afraid not. If you disable hires textures via that switch, no hires textures will work at all. What you can do is have a shortcut to D2X-XL, and if you right click that shortcut and go to "Properties" and add -pured2 to the end of the target statement, that shortcut will boot up D2X-XL in PureD2 mode, regardless of what your ini file says.
At least, this is how I used to do it... I hope this helps.
Install & setup problems, application questions and other nasty things ;)
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